Luminescence kinetics of linear polymer molecules with chromophores regularly distributed along the chain |
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| Authors: | E. N. Bodunov M. N. Berberan-Santos J. M. G. Martinho |
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| Affiliation: | (1) Russian State Hydrometeorological University, St. Petersburg, 195196, Russia;(2) Center of Chemical Physics of Molecules, Technical University, Lisbon, 1049-001, Portugal |
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| Abstract: | An analytical expression for luminescence kinetics of a polymer chain in the static regime is obtained for the case when the rotational motion of monomers, leading to the formation of excimers (traps of excitations), is frozen. The conditions are found when the inhomogeneous broadening of the chromophore spectra and the conformation motion of the polymer chain should be taken into account. |
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