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Bridged ring systems—XIII The synthesis of cycloheptene carboxylic acids |
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| Authors: | G L Buchanan A C W Curran J M McCrae and G W McLay |
| Institution: | Department of Chemistry, University of Glasgow Scotland |
| Abstract: | β-(2-Oxocyclopentyl)ethylaryl ketones are transformed under acid conditions via a 2-aryl-bicyclo3.2.1]oct-2-en-8-one intermediate into a mixture of arylcycloheptene carboxylic acids. The scope and the mechanism of the reaction are both discussed. |
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