A simple phenylation of heteroaromatic compounds using diphenyliodonium triflate |
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| Authors: | Qi Yang Jiao Chang Qun Wu Bianxiang Zhang |
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| Institution: | 1. School of Chemistry and Chemical Engineering, Shanxi University, 92 Wucheng Road, Taiyuan, 030006, People??s Republic of China
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| Abstract: | In this study a novel method for direct synthesis of 2-phenyl heteroaromatic arenes was successfully developed. The title compounds were synthesized by reaction of heteroaromatic compounds with diphenylene iodonium trifluoromethanesulfonate in the presence of 5?mol% Pd(OAc)2 under mild reaction conditions (THF, 60?°C, 24?h). The proposed reaction mechanism was studied by HPLC. |
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