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Infinite dilution activity coefficents of hydrocarbons in tetra-n-alkyltin solvents between 40 and 60°C measured by gas-liquid chromatography
Authors:Reynaldo C. Castells  Cecilia B. Castells
Affiliation:(1) CIDEPINT, 52 e/121 y 122, La Plata, Argentina;(2) Facultad de Ciencias Exactas, UNLP, 1900 La Plata, Argentina
Abstract:Infinite dilution activity coefficients for twenty-three hydrocarbons in tetra-n-amyltin (TAT) and in tetra-n-lauryltin (TLT) at several temperatures between 40 and 60°C were measured by gas liquid chromatography. The results, together with those obtained in an earlier paper in tetra-n-octyltin (TOT), are compared and discussed in terms of the equation of state theory of Flory and of the lattice fluid theory of Sanchez and Lacombe.
Keywords:Tetra-n-amyltin  tetra-n-octyltin  tetra-n-lauryltin  hydrocarbon solutions  infinite dilution activity coefficients  Flory theory  Sanchez-Lacombe theory  gas-liquid chromatography
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