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Influences of template concentration and epoxy functionality on porous epoxy systems: Characteristics of thermal stability, optical, dielectric, and mechanical properties
Authors:Chung-Feng Dai
Institution:Department of Chemistry and Center for Nanotechnology at CYCU, Chung Yuan Christian University, No. 200 Chung Pei Road, Chung Li 32023, Taiwan, ROC
Abstract:Two different multi-porous epoxy thermosets (MPETs), bi-functionality of DGEBA and tri-functionality of TGTPM, were prepared foremost for the interaction of template concentration and epoxy functionality under several physical properties. By performing an automated mercury porosimeter test, we found out template concentration was critical to the amount of voids/pores. Meanwhile, epoxy functionality decided the formation of porous structure through SEM. Comparing with TGTPM MPETs system, the DGEBA MPETs system with 20 wt% template displayed appreciable Tg and tan δ properties while the phenomenon exhibited higher thermal stability property. Additionally, thermal conductivity patterns show the DGEBA MPETs system is a remarkable material of thermal resistance. However, it reduces optical clarity, dielectric permittivity and mechanical strength according to the UV-visible spectroscopy, LCR meter, and DMA, normally. Therefore, we can understand that template concentration and epoxy functionality are key factors of physical degradation and stability in porous epoxy materials.
Keywords:Epoxy  Porous material  Thermal conductivity  Thermal stability
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