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EPR study of free radicals in a main chain thermotropic polymer
Authors:F Sz?cs  Z Hlou?ková
Institution:(1) Polymer Institute, Slovak Academy of Sciences, 842 36 Bratislava, Czechoslovakia
Abstract:Free radicals were generated in a rigid rod-like copolymer via mechanical route and by gamma radiation. The (EPR) method was used for studying free radicals formed at 123 K. The spectra of free radicals observed and the influence of molecular motions on the transport of radical centers in the fracture surface layer are discussed.
Keywords:Rigid rod-likecopolymers  (EPR)  free radicals  fracture and gamma irradiation
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