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Complexation between poly(methacrylic) and poly(acrylic) acids and star-shaped poly(ethylene glycol) based on pyrogallol
Authors:V Yu Baranovsky  S Shenkov  V Doseva  G Borisov
Abstract:Complex formation between polymethacrylic (PMAA) and polyacrylic acids, and star-shaped poly(ethylene glycol) prepared by ethoxylation of pyrogallol (Pyr–PEG) has been studied viscometrically and by potentiometric titration in water solution. The competitive ability of Pyr–PEG and of the derivatives of the ethoxylation of phenol and hydroquinone in complex formation with PMAA has been compared by UV spectroscopy. Pyr–PEG turns out to be the weakest competitor because of its chemical structure. © 1996 John Wiley & Sons, Inc.
Keywords:PMAA  polycomplex (PMAA  Pyr–  PEG)  UV spectra of polycomplexes (PMAA  PEG*)  competitive complexation
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