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Enantioselective [1,2]-Stevens rearrangement of quaternary ammonium salts. A mechanistic evaluation |
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| Authors: | Gonçalves-Farbos Maria-Héléna Vial Laurent Lacour Jérôme |
| Affiliation: | Department of Organic Chemistry, University of Geneva, Quai E. Ansermet 30, Geneva 4, Switzerland. |
| Abstract: | Using a supramolecular asymmetric ion pairing strategy, an enantioselective [1,2]-Stevens is feasible on substrates devoid of stereogenic quaternary nitrogen atoms. |
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