Catalytic dehydrocoupling of amine-borane and phosphine-borane adducts: the mechanism is heterogeneous in one case and homogeneous in the other |
| |
| Authors: | Jaska Cory A Manners Ian |
| |
| Institution: | Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada, M5S 3H6. |
| |
| Abstract: | The catalytic dehydrocoupling reactions of Me2NH.BH3 and Ph2PH.BH3 using the rhodium precatalyst Rh(1,5-cod)(mu-Cl)]2 were found to proceed by different mechanisms: heterogeneous involving Rh(0) metal for the former case and homogeneous for the latter. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
