Bis(ethylenedithio)tetrathiafulvalene bromide-ethylkne glycol: (BEDT-TTF)2Br·C2H4(OH)2. A new organic metal |
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| Authors: | E. I. Zhilyaeva R. N. Lyubovskaya N. P. Onishchuk S. V. Konovalikhin O. A. D'yachenko |
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| Affiliation: | (1) N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR |
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| Abstract: | A synthesis is reported for a new radical-cation salt (BEDT- TTF)2Br·C2H4(OH)2 having metallic electric conductance up to – 200 K. X-ray diffraction structural analysis was used to establish the existence of weak hydrogen bonds connecting the bromide ions with ethylene glycol molecules into infinite chains.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1438–1440, June, 1990.The authors thank R. B. Lyubovskii for measuring the electric conductance of a monocrystal of (I). |
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