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Ru3+及其它阳离子表面吸附对n-InP光电化学性能的影响
引用本文:钱道荪,杨镭. Ru3+及其它阳离子表面吸附对n-InP光电化学性能的影响[J]. 物理化学学报, 1986, 2(5): 444-451. DOI: 10.3866/PKU.WHXB19860509
作者姓名:钱道荪  杨镭
作者单位:Department of Applied Chemistry; Shanghai Jiao Tong University
摘    要:应用光阳极极化曲线, 电流-光强曲线、光谱响应曲线、平带电位以及电流相对增加与吸附时间之间的关系曲线研究了Ru~(3+)表面吸附对n-InP光电化学性能的影响, 还研究了其它一些阳离子吸附的影响。

收稿时间:1985-06-10
修稿时间:1986-04-14

EFFECTS OF SURFACE ADSORPTION WITH Ru3+ AND OTHER CATIONS ON THE PHOTOELECTROCHEMICAL PROPERTIES OF n-InP
Qian Daosun,Yang Lei. EFFECTS OF SURFACE ADSORPTION WITH Ru3+ AND OTHER CATIONS ON THE PHOTOELECTROCHEMICAL PROPERTIES OF n-InP[J]. Acta Physico-Chimica Sinica, 1986, 2(5): 444-451. DOI: 10.3866/PKU.WHXB19860509
Authors:Qian Daosun  Yang Lei
Affiliation:Department of Applied Chemistry; Shanghai Jiao Tong University
Abstract:In this the Paper effects of Ru~(3+) and other cations on the PEC properties of n-InP electrode are investigated.The adsorption of Ru~(3+) doesn't influence the photoanodic polarization curves of n-InP in Fe~(2+)/Fe~(3+) and Fe(CN)_6~(4-)/Fe(CN)_6~(3-) solutions but effects it in S~(2-)/S_x~(2-) solution significantly. A current peak is observed at -0.9 V vs. SCE. and the peak current varies linearly with the square root of the potential sweep rate but the peak potential is unchanged. The spectral response ...
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