| 无溶剂条件下碘催化合成三吲哚甲烷的研究 |
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| 引用本文： | 曾小飞,纪顺俊,苏晓明.无溶剂条件下碘催化合成三吲哚甲烷的研究[J].中国化学,2008,26(3):413-416. |
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| 作者姓名： | 曾小飞 纪顺俊 苏晓明 |
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| 作者单位： | 江苏省有机合成重点实验室，苏州大学化学化工学院，苏州工业园区，江苏，苏州, 215123 |
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| 摘 要： | 室温无溶剂条件下，碘(5 mol%)催化吲哚与原甲酸三乙酯的反应，生成相应的三吲哚甲烷，产率适中到较好且无副产物。
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| 关 键 词： | 吲哚 原甲酸三乙酯 对称的三吲哚甲烷 碘 无溶剂 |
| 收稿时间： | 2007-5-8 |
| 修稿时间： | 2007-6-22 |
Facile Synthesis of Symmetrical Triindolylmethanes Catalyzed by Iodine under Solvent‐free Condition |
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| Xiao‐Fei ZENG,Shun‐Jun JI,Xiao‐Ming SU.Facile Synthesis of Symmetrical Triindolylmethanes Catalyzed by Iodine under Solvent‐free Condition[J].Chinese Journal of Chemistry,2008,26(3):413-416. |
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| Authors: | Xiao‐Fei ZENG Shun‐Jun JI Xiao‐Ming SU |
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| Institution: | 1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Jiangsu 215123, China;2. Tel.: 0086‐0512‐65880086;3. Fax: 0086‐0512‐65880089 |
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| Abstract: | The reaction of various indoles ( 1a – 1k , 3 equiv.) with triethyl orthoformate (1.2 equiv.) catalyzed by I2 (5 mol%) at room temperature in 2–15 min under a solvent‐free condition afforded the respective symmetrical triindolylmethanes ( 3a – 3k ) in good to excellent yields without any side products. |
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| Keywords: | indole triethyl orthoformate symmetrical triindolylmethane iodine solvent‐free |
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