首页 | 本学科首页   官方微博 | 高级检索  
     


Possible scheme of synthesis-assembling of fullerenes
Authors:F. N. Tomilin  P. V. Avramov  S. A. Varganov  A. A. Kuzubov  S. G. Ovchinnikov
Affiliation:(1) Institute of Chemistry and Chemical Technology, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660049, Russia;(2) Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russia;(3) Krasnoyarsk State Technical University, Krasnoyarsk, 660074, Russia
Abstract:A new scheme of fullerene formation is proposed on the basis of the similarity between the experimentally detected carbon structures. According to experimental data, the microclusters of C2 and C10 are synthesized first and then either an intermediate nucleus cluster or an obtainable lower fullerene is assembled from them. A high-symmetry fullerene can be assembled with a high probability from a nucleus cluster with a “good” symmetry. The atomic and electronic structures of molecules such as C36, C60, C70, and C76 are analyzed. For C36, the NMR spectra are calculated and compared with the experimental data.
Keywords:
本文献已被 SpringerLink 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号