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Fast pyrolysis of rice straw,sugarcane bagasse and coconut shell in an induction-heating reactor
Institution:1. Department of Environmental Engineering and Science, Chia Nan University of Pharmacy and Science, Tainan 717, Taiwan;2. Department of Occupational Safety and Health, Chia Nan University of Pharmacy and Science, Tainan 717, Taiwan;1. State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan, Hubei 430070, China;2. School of Environmental Engineering, Wuhan Textile University, Wuhan 430073, China;1. Grupo Tayea, Facultad de Minas Universidad Nacional de Colombia, Medellin, Colombia;2. ECOPETROL, ICP, Pie de Cuesta, Santander, Colombia;1. Department of Environmental Science and Engineering, School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049, Shanxi, China;2. State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China;1. Sri Ramakrishna Engineering College, Coimbatore 641 022, India;2. Vellore Institute of Technology, Vellore 632 014, India;3. Sri Sairam Engineering College, Chennai 600 044, India;1. Thermo-Catalytic Processes Area (TPA), Bio-Fuels Division (BFD), CSIR-Indian Institute of Petroleum (IIP), Dehradun, 248005, India;2. Academy of Scientific and Innovative Research (AcSIR), New Delhi, India;3. Department of Chemistry, A.S. College, Samrala Road, Khanna, 141402, India;4. Analytical Sciences Division (ASD), CSIR-Indian Institute of Petroleum, Dehradun, India
Abstract:With the application of induction heating, a fast pyrolysis was used for producing valuable products from rice straw, sugarcane bagasse and coconut shell in an externally heated fixed-bed reactor. The effect of process parameters such as pyrolysis temperature, heating rate and holding time on the yields of pyrolysis products and their chemical compositions were investigated. The maximum yield of ca. 50% on the pyrolysis liquid product could be obtained at the proper process conditions. The chemical characterization by elemental (CHNO), calorific, Fourier transform infrared (FT-IR) spectroscopy and gas chromatography/mass spectrometry (GC–MS) showed that the pyrolysis liquid products contain large amounts of water (>65 wt.%), and fewer contents of oxygenated hydrocarbons composing of carbonyl groups, resulting in low pH and low heating values. The results were very similar to bio-oils obtained from other biomass materials. The residual solid (char or charcoal) was also characterized in the present study.
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