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Research Progress on Triarylmethyl Radical-Based High-Efficiency OLED
Authors:Jie Luo  Xiao-Fan Rong  Yu-Yuan Ye  Wen-Zhen Li  Xiao-Qiang Wang  Wenjing Wang
Institution:College of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China; (J.L.); (X.-F.R.); (Y.-Y.Y.); (W.-Z.L.)
Abstract:Perchlorotrityl radical (PTM), tris (2,4,6-trichlorophenyl) methyl radical (TTM), (3,5-dichloro-4-pyridyl) bis (2,4,6 trichlorophenyl) methyl radical (PyBTM), (N-carbazolyl) bis (2,4,6-trichlorophenyl) methyl radical (CzBTM), and their derivatives are stable organic radicals that exhibit light emissions at room temperature. Since these triarylmethyl radicals have an unpaired electron, their electron spins at the lowest excited state and ground state are both doublets, and the transition from the lowest excited state to the ground state does not pose the problem of a spin-forbidden reaction. When used as OLED layers, these triarylmethyl radicals exhibit unique light-emitting properties, which can increase the theoretical upper limit of the OLED’s internal quantum efficiency (IQE) to 100%. In recent years, research on the luminescent properties of triarylmethyl radicals has attracted increasing attention. In this review, recent developments in these triarylmethyl radicals and their derivatives in OLED devices are introduced.
Keywords:organic radicals  OLED  room-temperature luminescence  open-shell  doublet state
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