| 微波辐射FeCl3催化无溶剂条件下的呐醇重排 |
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| 引用本文： | 边延江,贾志强. 微波辐射FeCl3催化无溶剂条件下的呐醇重排[J]. 有机化学, 2009, 29(6): 975-978 |
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| 作者姓名： | 边延江 贾志强 |
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| 作者单位： | (廊坊师范学院化学系 廊坊 065000) |
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| 摘 要： | 通过微波辐射, 以FeCl3为催化剂进行无溶剂条件下的呐醇重排反应, 1 min产率可达86%～96%. 该方法具有操作简便、反应时间缩短、对环境友好等优点.
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| 关 键 词： | 呐醇重排 微波辐射 无溶剂 路易斯酸 |
| 收稿时间： | 2008-07-02 |
| 修稿时间： | 2008-11-06 |
Solventless Pinacol Rearrangement Catalysed by FeCl3 under Microwave Irradiation |
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| Affiliation: | (Department of Chemistry, Langfang Normal College, Langfang 065000) |
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| Abstract: | The pinacol rearrangement catalysed by FeCl3 in the absence of solvent was carried out. The pinacolones were obtained in yields of 86%～96% for 1 min under microwave irradiation, which provided several advantages such as simple work-up procedure, shorter reaction time, and environmental friendliness. |
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| Keywords: | pinacol rearrangement microwave irradiation solventless Lewis ac |
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