| 摘 要： | Chiralrecognitionphenomenaplayanimportantroleinavarietyofchemical,physicalandbiologicalprocesses-SinceCramandhiscoworkerspublishedtheirfirstpioneeringstudiesontheuseofchiralmacrocyclicligandsinenantiomericrecognition,manychiralmacrocycleshavebeensynthesizedandusedinchiralrecognition'~'-Sulfuratomissoftbase.Thesulfur-containingchiralmacrocyclicligandscanformcomplexwithtransitionmetalsandhavepotentialapplicationinasymmetricsynthesisandchiralrecognition,butlittlestudyofsynthesisandapplicationhasb…
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