| 气相转移法制备ZnAPO-34分子筛膜 |
| |
| 引用本文： | 曾昌凤,张利雄,王焕庭,徐南平.气相转移法制备ZnAPO-34分子筛膜[J].高等学校化学学报,2004,25(2):204-207. |
| |
| 作者姓名： | 曾昌凤 张利雄 王焕庭 徐南平 |
| |
| 作者单位： | 1. 南京工业大学机械与动力工程学院;
2. 南京工业大学化学化工学院, 南京 210009;
3. 香港大学化学系, 香港 |
| |
| 基金项目： | 国家自然科学基金 (批准号 :2 0 14 10 0 3和 2 0 2 0 10 0 7)资助 |
| |
| 摘 要： | 采用气相转移法在致密氧化铝陶瓷片上制备了ZnAPO-34薄膜,并用XRD和SEM对其进行了表征.结果发现,合成配方中水的含量对ZnAPO-34粉末和膜的晶体大小和形貌有很大的影响,而且对成功制备连续的ZnAPO-34膜至关重要.在固相配比为n(P2O5);n(Al2O3);n(ZnO);n(H2O)=1;0.8;0.4;150,液相为1;75(摩尔比)的三乙胺-水溶液中,于170℃反应24h的条件下,经重复合成可得到连续无缺陷的ZnAPO-34分子筛膜.
|
| 关 键 词： | 分子筛膜 气相转移法 ZnAPO-34膜 |
| 文章编号： | 0251-0790(2004)02-0204-04 |
| 收稿时间： | 2003-06-02 |
Synthesis of ZnAPO-34 Films by Vapor-phase Transport Method |
| |
| ZENG Chang-Feng ,ZHANG Li-Xiong ,WANG Huan-Ting ,XU Nan-Ping.Synthesis of ZnAPO-34 Films by Vapor-phase Transport Method[J].Chemical Research In Chinese Universities,2004,25(2):204-207. |
| |
| Authors: | ZENG Chang-Feng ZHANG Li-Xiong WANG Huan-Ting XU Nan-Ping |
| |
| Institution: | 1. College of Mechanic and Dynamic Engineering;
2. College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China;
3. Department of Chemistry, Hong Kong University, Hong Kong, China |
| |
| Abstract: | ZnAPO-34 films on dense alumina plates were synthesized by the vapor-phase transport(VPT) method. XRD and SEM were used to examine the powders and films. The water content in the synthesis had a strong influence on the crystal sizes and the morphology of ZnAPO-34 powders and films, and played a critical role on the successful preparation of a uniform ZnAPO-34 film. The optimum VPT synthesis was conducted at 170 ℃ for 24 h with the gel prepared as a composition of n(P2O5);n(Al2O3);n(ZnO);n(H2O)=1;0.8;0.4 ;150 and the liquid phase composed of triethylamine and water n(triethylamine);n(H2O)=1;75]. Repeated synthesis cycles were necessary to obtain a continuous and uniform ZnAPO-34 film. |
| |
| Keywords: | Molecular sieve film Vapor-phase transport method ZnAPO-34 film |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
