Dehydroiodination of 2-iodo-3-(polyfluoroalkyl)propoxymethyloxiranes |
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| Authors: | D N Bazhin T I Gorbunova A Ya Zapevalov V I Saloutin |
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| Institution: | (1) I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620041 Ekaterinburg, Russian Federation |
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| Abstract: | Dehydroiodination of 2-iodo-3-(polyfluoroalkyl)propoxymethyloxiranes upon treatment with 1,8-diazabicyclo5.4.0]undec-7-ene
(DBU) afforded (polyfluoroalk-2-enyl)oxymethyloxiranes as E-and Z-isomers in ratio depending on the nature of the fluoroalkyl substituent.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2160–2162, November, 2007. |
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| Keywords: | glycidyl ethers dehydroiodination olefins organofluorine compounds |
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