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Electrochemical co-oxidation of C-H acids and methanol as a new route to functionalized cyclopropanes
Authors:S K Fedukovich  M N Elinson  G I Nikishin
Institution:(1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Russian Federation
Abstract:Electrolysis of dimethyl malonate or methyl cyanoacetate in methanol in the presence of LiCl in an undivided cell leads to formation of 1,1,2,2-cyclopropanetetracarboxylic derivatives.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1835–1836, October, 1994.This work was supported by the International Science Foundation (Grant No MHY 000).
Keywords:electrochemical oxidation  malonic ester  cyanoacetyc ester  1  1  2  2-cyclopropanecarboxylic acid
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