Phase relations up to the solidus line in the part of the Sb-Zn-O system |
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Authors: | Elżbieta Filipek Grażyna Dąbrowska |
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Institution: | (1) Department of Inorganic and Analytical Chemistry, Szczecin University of Technology, 71-065 Szczecin, Poland |
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Abstract: | Phase relations up to the solidus line in part of the Sb-Zn-O system have been investigated over the entire concentration
range of the α-Sb2O4-ZnO system in air (= 0.21 atm) using XRD and DTA/TG. The components of this system in air form ZnSb2O6 and Zn7Sb2O12. The results allow division of the system into three subsystems, i.e. α-Sb2O4-ZnSb2O6; ZnSb2O6Zn7Sb2O12 and Zn7Sb2O12-ZnO. The temperature ranges over which the ZnSb2O6 and Zn7Sb2O12 remain at equilibrium with other solid compounds depend on the gaseous atmosphere.
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