First hexadecavanadate compound: hydrothermal synthesis and characterization of a three-dimensional framework [(Cu(1,2-pn)2)7(V16O38(H2O))2].4H2O |
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| Authors: | Lin Bi-Zhou Liu Shi-Xiong |
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| Institution: | Department of Chemistry, Fuzhou University, wFuzhou 350002, P. R. China. bzlin@hqu.edu.cn |
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| Abstract: | The hydrothermal reaction of V2O5, Cu(CH3COO)2.H2O, 1,2-diaminopropane and N(CH3)4]OH yields the novel three-dimensional open-framework solid (Cu(1,2-pn)2)7-(V16O38(H2O))2].4H2O constructed from the new mixed-valence V16O38(H2O)]7- clusters interconnected through mu 2-Cu(1,2-pn)2]2+ groups. |
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