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How Common Are True Aminopyridinato Complexes? |
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| Authors: | Stefan Deeken Günter Motz Rhett Kempe Prof Dr |
| Institution: | 1. Bayreuth, Universit?t, Lehrstuhl Anorganische Chemie II;2. Bayreuth, Universit?t, Lehrstuhl Keramische Werkstoffe;3. Bayreuth, Universit?t, Lehrstuhl Anorganische Chemie IILehrstuhl Anorganische Chemie II, Universit?t Bayreuth, D‐95440 Bayreuth, Germany |
| Abstract: | An overview over the binding situation in transition metal and lanthanide aminopyridinato complexes is given. True aminopyridinato complexes in which we observe a significant longer N‐amido than N‐pyridine bond length are rare and for instance observed for ruthenium. Additional examples of ruthenium aminopyridinato complexes were synthesized and characterized by X‐ray crystal structure analysis. |
| Keywords: | Amido ligands Aminopyridinato ligands Ruthenium |