Rhenium Trichloride Dioxide,ReO2Cl3, Preparation and Reactions |
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| Authors: | Joanna Supeł Konrad Seppelt Prof. Dr. |
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| Affiliation: | 1. Berlin, Freie Universit?t, Institut für Chemie, Anorganische und Analytische Chemie;2. Berlin, Freie Universit?t, Institut für Chemie, Anorganische und Analytische ChemieFreie Universit?t Berlin, Institut für Chemie, Anorganische and Analytische Chemie, Fabeckstra?e 34‐36, D‐14195 Berlin, Fax: ++49 30 83853310 |
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| Abstract: | A one step synthesis of ReO2Cl3 is reported. ReO2Cl3 reacts with [(C2H5)4P]+Cl?, forming [(C2H5)4P]+[cis–ReO2Cl4]?, a = 1257.0(2), b = 1026.8(2), c = 1277.9(2) pm, β = 106.659(3)°, P21/n. Also an unstable NO+[ReO2Cl4]? can be obtained from NOCl and ReO2Cl3. With the Lewis acid GaCl3 the zwitter ion [ReO2Cl2]+[GaCl4]? is formed. a = 1184.0(3), b = 829.2(2), c = 1100.8(2) pm, β = 112.98(1)°, P21/c. |
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| Keywords: | Rhenium Rhenium trichloride dioxide Tetrachlorodioxorhenate(VII) Dichlorodioxorhenium(VII) |
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