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Attempted Abstraction of the Halogenides in (HNEt3)[Re(CH3CN)2Cl4] and Crystal Structures of cis‐[Re(CH3CN)2Cl4]·CH3CN and cis‐[Re(NHC(OCH3)CH3)2Cl4] |
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| Authors: | Peter C. Kunz Dr. Philipp Kurz Bernhard Spingler Roger Alberto |
| Affiliation: | 1. Zürich / Switzerland, University Zürich‐Irchel, Institute of Inorganic Chemistry;2. Current address: Düsseldorf, Heinrich‐Heine‐Universit?tHeinrich‐Heine‐Universit?t Düsseldorf, Universit?tsstr. 1, D‐40225 Düsseldorf/Germany, Fax: (+49) 211 8112287;3. Current address: University of Uppsala, Sweden |
| Abstract: | The abstraction of the halogenide ligands in [Re(CH3CN)2Cl4]? should result in a solvent‐only stabilized ReIII complex. The reactions of salts of [Re(CH3CN)2Cl4]? with silver(I) and thallium(I) salts were investigated and the solid‐state structures of cis‐[Re(CH3CN)2Cl4]·CH3CN and cis‐[Re(NHC(OCH3)CH3)2Cl4] are described. |
| Keywords: | Rhenium Halogenide Abstraction Crystal structures |