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Attempted Abstraction of the Halogenides in (HNEt3)[Re(CH3CN)2Cl4] and Crystal Structures of cis‐[Re(CH3CN)2Cl4]·CH3CN and cis‐[Re(NHC(OCH3)CH3)2Cl4]
Authors:Peter C Kunz Dr  Philipp Kurz  Bernhard Spingler  Roger Alberto
Institution:1. Zürich / Switzerland, University Zürich‐Irchel, Institute of Inorganic Chemistry;2. Current address: Düsseldorf, Heinrich‐Heine‐Universit?tHeinrich‐Heine‐Universit?t Düsseldorf, Universit?tsstr. 1, D‐40225 Düsseldorf/Germany, Fax: (+49) 211 8112287;3. Current address: University of Uppsala, Sweden
Abstract:The abstraction of the halogenide ligands in Re(CH3CN)2Cl4]? should result in a solvent‐only stabilized ReIII complex. The reactions of salts of Re(CH3CN)2Cl4]? with silver(I) and thallium(I) salts were investigated and the solid‐state structures of cis‐Re(CH3CN)2Cl4]·CH3CN and cis‐Re(NHC(OCH3)CH3)2Cl4] are described.
Keywords:Rhenium  Halogenide Abstraction  Crystal structures
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