Synthesis,Characterization, and Crystal Structures of a New Coordination Polymer of Manganese(II) Containing Dimethyl Phosphate |
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| Authors: | Masoud Rafizadeh Dr Vahid Amani Himan Farajian |
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| Institution: | 1. Tehran/Iran, Teacher Training University, Department of ChemistryDepartment of Chemistry, Reacher Training University, 49 Mofateh Avenue, 15614 Tehran / Iran;2. Tehran/Iran, Islamic Azad University, Shat‐e‐Ray Branch;3. Tehran/Iran, Teacher Training University, Department of Chemistry |
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| Abstract: | The reaction of MnCl2 with TMP (TMP = Trimethyl phosphate) in THF (THF = tetrahydroforan), led to the coordination polymer Mn2(μ3‐DMP)2(μ‐DMP)2]n (1) (DMP = dimethyl phosphate). This complex was characterized by elemental analysis, IR spectroscopy and single‐crystal structure of 1 . Crystal data for 1 at ?173 °C: triclinic, space group  , a = 9.7071(11), b = 10.4482(11), c = 10.6242(11) Å, α = 88.892(2)°, β = 80.829(2)°, γ = 87.572(2)°, Z = 2, R1 = 0.0441. |
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| Keywords: | Manganese Trimethyl phosphate Dimethyl phosphate Crystal structure |
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