An Ortho‐silicate‐hydroxide: Rb5[SiO4][OH] |
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| Authors: | Oliver Kerp Angela Möller Priv.‐Doz. Dr. |
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| Affiliation: | 1. K?ln, Institut für Anorganische Chemie der Universit?t;2. K?ln, Institut für Anorganische Chemie der Universit?tInstitut für Anorganische Chemie der Universit?t zu K?ln, Greinstra?e 6, D‐50939 K?ln |
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| Abstract: | Rb5[SiO4][OH] crystallizes in the monoclinc space group C2/m with a = 737.3(1) pm, b = 1073.7(2) pm, c = 1207.2(2) pm, β = 106.07(2)° and Z = 4 (single crystal data; R1= 0.0681 all data). Layers of edge‐connected distorted trigonal prismatic [(OH)Rb6] entities and isolated tetrahedral [SiO4] units present the main structural features of this unprecedented structure type. |
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| Keywords: | Silicates Hydroxides Rubidium Crystal structure |
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