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Diethylenetriammonium Aquapentachloroferrate(III) Chloride: Structure and Magnetic Properties |
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| Authors: | Bruce D. James Dr. Jerzy Mrozinski Prof. Dr. Julia Klak Brian W. Skelton Allan H. White |
| Affiliation: | 1. Bundoora/Victoria, 3086, Australia, La Trobe University, Department of Chemistry;2. Bruce D. James, Department of Chemistry, La Trobe University, Vic. 3086, Australia. Tel.: +61 3 9479 2534, Fax.: +61 3 9479 1399;3. Jerzy Mrozinski, Faculty of Chemistry, University of Wroclaw, F. Joliot‐Curie 14, 50‐383 Wroclaw, Poland, Tel.: +48 71 375 7307, Fax.: +48 71 328 2348;4. Wroclaw/Poland, 50‐383, University of Wroclaw, Department of Chemistry;5. Crawley/Western Australia, 6009, The University of Western Australia, School of Biomedical, Biomolecular and Chemical Sciences, Chemistry M313 |
| Abstract: | Diethylenetriamine (dien) and iron(III) chloride in aqueous HCl yield (dienH3) [FeCl5(H2O)]Cl, in which the chloroferrate(III) anion is significantly distorted from octahedral symmetry due to the extensively hydrogen‐bonded lattice. On cooling, the high spin FeIII material shows weak antiferromagnetic coupling that results in a Néel temperature of 2.70 K. |
| Keywords: | Iron Aquapentachloroferrate(III) Diethylenetriammonium salt Crystal structure Magnetic properties |