Synthesis and Characterization of a New Organically Templated Aluminophosphite with a Chainlike Structure |
| |
| Authors: | Yong Xiang Lin‐Wen Zhang Wu‐Hua Chen Jian‐Zhong Chen Qing‐Xin Zeng Dr |
| |
| Institution: | 1. Fuzhou, Fujian/China, Department of Chemistry, Fuzhou University;2. Fuzhou, Fujian/China, Department of Chemistry, Fuzhou UniversityDepartment of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China |
| |
| Abstract: | A new aluminophosphite (H4bape)0.5Al(OH)(HPO3)2] has been synthesized under hydrothermal conditions and its structure was determined by single‐crystal X‐ray diffraction (bape = N,N′‐bis(2‐aminopropyl)ethylenediamine). This compound crystallizes in the triclinic system with the space group  (No. 2), a = 6.919(2) Å, b = 8.704(2) Å, c = 9.786(2) Å, α = 77.74(3)°, β = 72.43(3)°, γ = 72.52(3)°, V = 531.08(2) Å3, Z = 2. The structure consists of distorted octahedral AlO6 and pseudo pyramidal HPO3, which are connected by vertex oxygen atoms to form a chainlike framework with a Al/P ratio of 1/2. The presence of 1D infinite Al‐O‐Al linkage in the framework is noteworthy. The organic templates are fully protonated and interact with the aluminophosphite chains through extensive hydrogen bonds to form a 3D supramolecular network. |
| |
| Keywords: | Hydrothermal synthesis Characterization Organic template Aluminophosphite Crystal elucidation |
|
|
