Single Crystal of a Prussian Blue Analog based on Rubidium Manganese Hexacyanoferrate |
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| Authors: | Hiroko Tokoro Motoo Shiro Kazuhito Hashimoto Shin‐ichi Ohkoshi Prof. Dr. |
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| Affiliation: | 1. Tokyo / Japan, The University of Tokyo, School of Science, Department of Chemistry;2. Tokyo / Japan, The University of Tokyo, School of Science, Department of Physics;3. Tokyo / Japan, The University of Tokyo, School of Science, School of Engineering, Department of Applied Chemistry;4. Tokyo / Japan, Rigaku Corporation;5. Tokyo / Japan, The University of Tokyo, School of Science, School of Engineering, Department of Applied ChemistryDepartment of Chemistry, School of Science, The University of Tokyo, 7‐3‐1 Hongo, Tokyo / Japan 113‐0033 |
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| Abstract: | A dark brown single crystal of rubidium manganese hexacyanoferrate, Rb0.61Mn[Fe(CN)6]0.87·1.7H2O, was obtained by the slow diffusion method. X‐ray single crystal analysis showed that this compound crystallized in the cubic system of space group  with cell constants of a = b = c = 10.5354(4) Å, Z = 4, and R1 = 0.0449. The CN groups bridge octahedral FeC6 and MnN0.87O0.13. Rb and non‐coordinated water (so‐called zeolitic water) exist in the interstitial sites of the cubic lattice. |
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| Keywords: | Crystal structure Prussian blue analog Cyanide‐bridged metal complexes |
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