Synthese und Festkörperstruktur des Koordinationspolymers {Zn[Sn(CH2SMe)4]0.5Cl2}n |
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| Authors: | Kai Ruth Manuela Müller Michael Bolte Jan W Bats Matthias Wagner Hans‐Wolfram Lerner Dr |
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| Institution: | 1. Frankfurt, Institut für Anorganische Chemie der Johann Wolfgang Goethe‐Universit?t;2. Frankfurt, Institut für Organische Chemie der Johann Wolfgang Goethe‐Universit?t;3. Frankfurt, Institut für Anorganische Chemie der Johann Wolfgang Goethe‐Universit?tInstitut für Anorganische Chemie, Johann Wolfgang Goethe‐Universit?t, Max‐von‐Laue‐Stra?e 7, D‐60438 Frankfurt am Main, Fax: ++49‐69‐798‐29260 |
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| Abstract: | Synthesis and Solid State Structure of the Coordination Polymer {ZnSn(CH2SMe)4]0.5Cl2}n The tin compounds Sn(CH2SMe)4 and Sn(CH2PPh2)4 are accessible from reaction of SnCl4 with LiCH2SMe and LiCH2PPh2, respectively. X‐ray quality crystals of Sn(CH2PPh2)4 (tetragonal,  ) are obtained from a benzene solution at 4 °C. The lithium methanide Li(PMDTA)CH2PPh2], which was a starting material in the synthesis of Sn(CH2PPh2)4 crystallized from a mixture of diethyl ether and pentane at ?20 °C in the monoclinic space group P21/c. The coordination polymer {ZnSn(CH2SMe)4]0.5Cl2}n was synthesized from Sn(CH2SMe)4 and ZnCl2 in benzene. The solid state structure of this coordination polymer reveals that {ZnSn(CH2SMe)4]0.5Cl2}n possesses an infinite Zn‐SMe‐CH2‐Sn‐CH2‐SMe‐]‐chain as its backbone (monoclinic P21/c). |
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| Keywords: | Phosphanes Thio ethers Tin Zinc Coordination polymers Crystal structure |
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