Fluordiazadiphosphetidine, 5. Mitt. |
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| Authors: | Manfred Kubjacek Kurt Utvary |
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| Institution: | (1) Institut für Anorganische Chemie, Technische Universität Wien, A-1060 Wien, Österreich |
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| Abstract: | Reaction of (CH3NPF3)2 with equimolar amounts of N-methylhexamethyldisilazane yields a reaction product, which can be separated in a polymer and a crystalline fraction. High-vacuum sublimation of the crystalline part yields the already known compound (CH3N)4P3F7, the new spiro-isomer F3P(CH3N)2PF(CH3N)2PF3 and the spiro-compound F3P(CH3N)2PF(CH3N)2PF(CH3N)2PF3, an isomer of the known compound (CH3N)6P4F8. |
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