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Electronic structure of benzenechromium tricarbonyl derivatives: The loss of conjugation between the π-aromatic system and the substituent of the coordinated ligand
Authors:Yu. V. Chizhov  M. M. Timoshenko  G. S. Medynskii  V. N. Baidin  M. E. Akopyan  N. I. Vasyukova  Yu. S. Nekrasov
Affiliation:(1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow;(2) Physics Research Institute, A. A. Zhdanov Leningrad State University, USSR
Abstract:Conclusions A study of the photoelectron spectra of benzenechromium tricarbonyl derivatives indicates the virtually complete loss of conjugation between the pgr-aromatic system and the substituent of the coordinated ligand.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1425–1427, June, 1985.The authors express their gratitude to N. K. Baranetskaya and V. I. Losilkina for providing samples of the benzenechromium tricarbonyl derivatives studied.
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