Metal oxo complexes as catalysts for the isomerisation of allylic alcohols |
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| Institution: | Laboratoire de chimie organométallique et de catalyse, UMR 7513 CNRS, institut Le Bel, université Louis-Pasteur, 4, rue Blaise-Pascal, 67070 Strasbourg, France |
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| Abstract: | The 1,3-allylic rearrangement of allylic alcohols is an important transformation in organic synthesis and various methods for effecting such a transposition have been reported. This short review will focus on the development of transition metal oxo complexes as catalysts for the isomerisation of allylic alcohols. Mechanistic investigations are also discussed. |
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