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Living ROMP Synthesis and Redox Properties of Diblock Ferrocene/Cobalticenium Copolymers |
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| Authors: | Roberto Ciganda,Haibin Gu,Patricia Castel,Penxiang Zhao,Jaime Ruiz,Ricardo Herná ndez,Didier Astruc |
| Abstract: | Using the third‐generation Grubbs catalyst, the living ring‐opening metathesis polymerization of ferrocene/cobalticenium copolymers is conducted with theoretical numbers of 25 monomer units for each block, and their redox and electrochemical properties allow using the Bard–Anson electrochemical method to determine the number of metallocenyl units in each block.  |
| Keywords: | cobalticenium electrochemistry ferrocene metallopolymers ring‐opening metathesis polymerization, ROMP |