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Synthesis and chemical characterization of oxynitride apatites
Institution:1. School of Materials Science and Engineering, Harbin Institute of Technology, 92 West Da-Zhi Street, Harbin 150001, China;2. School of Materials Science and Engineering, Liaoning University of Technology, 169 Shi Ying Street, Jinzhou 121001, China;1. Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, Xinjiang Technical Institute of Physics & Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;3. Department of Physics, School of Science, Shihezi University, Shihezi 832000, China;4. Engineering Department of Chemistry and Environment, Xinjiang Institute of Engineering; 236 Nanchang Road, Urumqi 830091, China;1. School of Science, Chongqing University of Technology, 69 Hongguang Street, Chongqing 400054, China;2. Department of Mathematics and Physics, Chongqing University of Posts and Telecommunications, Chongqing 400065, China;1. Laboratoire de physique des Matériaux, Faculté des Sciences de Bizerte, Université de Carthage, Zarzouna 7021, Tunisia;2. Laboratoire de Physique des Matériaux Lamellaires et Nano-Matériaux Hybrides, Faculté des Sciences de Bizerte, Université de Carthage, Zarzouna 7021, Tunisia;3. Instituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciónes Científicas (CSIC), Cantoblanco, 28049 Madrid, Spain;1. School of Materials Science and Engineering, Harbin Institute of Technology, 92 West Da-Zhi Street, Harbin 150001, China;2. School of Materials Science and Engineering, Liaoning University of Technology, 169 Shi Ying Street, Jinzhou 121001, China
Abstract:New oxynitride apatites Ln10Si6O24N2 and the mixed compounds Ln110−xLn2x(Si6O22N2)O2, with Ln = La, Ce, Nd, Sm, Gd, were synthesized and investigated. It was shown that the oxidation of the mixed Ln110−xLn2x(Si6O22N2)O2 leads to the corresponding oxygenated apatites.
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