Intramolecular additions of alcohols and carboxylic acids to inert olefins catalyzed by silver(I) triflate |
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| Authors: | Yang Cai-Guang Reich Nicholas W Shi Zhangjie He Chuan |
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| Affiliation: | Department of Chemistry, University of Chicago, 5735 South Ellis Avenue, Chicago, Illinois 60637, USA. |
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| Abstract: | [reactions: see text] Intramolecular additions of hydroxyl or carboxyl groups to inert olefins catalyzed by simple silver(I) triflate are described. Good to excellent yields can be obtained for a range of substrates under relatively mild conditions. This reaction represents one of the simplest methods to construct cyclic ethers or lactones. |
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