Non-racemic (scalemic) planar-chiral five-membered metallacycles: routes, means, and pitfalls in their synthesis and characterization |
| |
Authors: | Djukic Jean-Pierre Hijazi Akram Flack Howard D Bernardinelli Gérald |
| |
Affiliation: | Laboratoire de Synthèses Métallo-induites, Institut de Chimie de Strasbourg, Université Louis Pasteur, 4 rue Blaise Pascal, F-67000 Strasbourg, France. djukic@chimie.u-strasbg.fr |
| |
Abstract: | This critical review provides a systematic classification of the synthetic routes to planar-chiral five-membered metallacycles into several routes, namely C-H bond activation, oxidative addition, transmetallation and optical resolution. As a characteristic of these bulk compounds is that they are synthesized as binary mixtures of enantiomers in proportions varying from the racemate to enantiopure, a review of absolute-configuration determination of the title planar-chiral scalemates is presented. This review is of interest to organic and organometallic synthetic chemists involved in asymmetric synthesis (97 references). |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|