| Triton X-100推动碱金属离子在液/液界面上转移的机制和伏安行为 |
| |
| 引用本文： | 孙志胜,汪尔康.Triton X-100推动碱金属离子在液/液界面上转移的机制和伏安行为[J].化学学报,1990,48(9):898-902. |
| |
| 作者姓名： | 孙志胜 汪尔康 |
| |
| 作者单位： | 中国科学院电分析化学开放研究实验室 |
| |
| 摘 要： | 本文用四电极循环伏安法研究了非离子型表面活性剂Triton X-100推动碱金属离子K^+, Na^+等在水/硝基苯, 水/1,2-二氯乙烷界面上的转移过程, 根据实验结果提出Triton X-100推动金属离子转移的一种机制, 推导了转移半波电位方程式, 并用实验进行了验证。
|
| 关 键 词： | 水 钠 钾 硝基苯 非离子表面活性剂 二氯乙烷 电化学反应 ＴＲＩＴＯＮＸ-１００ 循环伏安法 碱金属离子 |
Cyclic voltammetric study on the transfer mechanism of alkali metal ions across liquid-liquid interface facilitated by Triton X-100 |
| |
| SUN ZHISHENG,WANG ERKANG.Cyclic voltammetric study on the transfer mechanism of alkali metal ions across liquid-liquid interface facilitated by Triton X-100[J].Acta Chimica Sinica,1990,48(9):898-902. |
| |
| Authors: | SUN ZHISHENG WANG ERKANG |
| |
| Abstract: | The transfer behavior of alkali metal ions K+ and Na+ across the interfaces of water/nitrobenzene and water/1,2-dichloroethane facilitated by Triton X-100 is investigated by cyclic voltammetry with four electrodes. The equations of interfacial half-wave potential derived in terms of the mechanism proposed is verified by the experimental data. |
| |
| Keywords: | WATER SODIUM POTASSIUM NITROBENZENE NON IONIC SURFACTANTS DICHLOROETHANE ELECTROCHEMICAL REACTION TRITON X-100 CYCLOVOLTAMGRAPH ALKALI METAL ION |
| 本文献已被 维普 等数据库收录！ |
| 点击此处可从《化学学报》浏览原始摘要信息 |
| 点击此处可从《化学学报》下载免费的PDF全文 |
