| 应用晶体结构数据进行化学反应途径研究 Ⅰ. 五配位钼化合物Mo(L)5的动态立体化学 |
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| 引用本文： | 廖代清,傅亨,唐有祺.应用晶体结构数据进行化学反应途径研究 Ⅰ. 五配位钼化合物Mo(L)5的动态立体化学[J].物理化学学报,1987,3(5):449-452. |
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| 作者姓名： | 廖代清 傅亨 唐有祺 |
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| 作者单位： | Institute of Chemistry; Academia Sinica; Beijing; China |
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| 摘 要： |
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| 收稿时间： | 1987-04-29 |
| 修稿时间： | 1987-05-19 |
THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS,I. DYNAMIC STEREOCHEMISTRY OF FIVECOORDINATE MOLYBDENUM COMPOUNDS Mo(L)5 |
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| Liao Daiqing,Fu Heng,Tang Yougi.THE APPLICATION OF STRUCTURAL DATA TO THE RESEARCH ON CHEMICAL REACTION PATHWAYS,I. DYNAMIC STEREOCHEMISTRY OF FIVECOORDINATE MOLYBDENUM COMPOUNDS Mo(L)5[J].Acta Physico-Chimica Sinica,1987,3(5):449-452. |
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| Authors: | Liao Daiqing Fu Heng Tang Yougi |
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| Institution: | Institute of Chemistry; Academia Sinica; Beijing; China |
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| Abstract: | The principle of structure correlation is applied to 28 crystal structures which contain 44 different five-coordinate molybdenum fragments. The data derived map the reaction pathway for a bimolecular ligand substitution reaction at tetrahedral molybdenum centers. The dihedral-angle method from Muetterties and Guggenberger is employed in order to describe the interconversion between the trigonal bipyramidal (TBP) and the square pyramidal (SQP) conformations via the Berry pseudorotation mechanism in the system of Mo(L)_5 complexes. This structure correlation method provides a convincing mapping of the Berry pathway in this paper. |
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