Synthesis of the first unsymmetrical 34-electron cationic cobalt-nickel triple-decker complex with a central cyclopentadienyl ligand [(η-C6Me6)Co(μ-η:η-C5H5)Ni(η-C5H5)]PF6 |
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Authors: | A R Kudinov D V Muratov P V Petrovskii M I Rybinskaya |
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Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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Abstract: | The first unsymmetrical 34-electron cationic cobalt-nickel triple-decker complex with a central cyclopentadienyl ligand (η-C6Me6)Co(μ-η:η-C5H5)Ni(η-C5)PF6 was prepared by the reaction of (η-C6Me6)2Co]PF6 with nickelocene.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 798–799, April, 1999. |
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Keywords: | triple-decker complexes sandwich compounds cobalt complexes nickel complexes |
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