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Synthesis of the first unsymmetrical 34-electron cationic cobalt-nickel triple-decker complex with a central cyclopentadienyl ligand [(η-C6Me6)Co(μ-η:η-C5H5)Ni(η-C5H5)]PF6
Authors:A. R. Kudinov  D. V. Muratov  P. V. Petrovskii  M. I. Rybinskaya
Affiliation:(1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation
Abstract:The first unsymmetrical 34-electron cationic cobalt-nickel triple-decker complex with a central cyclopentadienyl ligand [(η-C6Me6)Co(μ-η:η-C5H5)Ni(η-C5)PF6 was prepared by the reaction of [(η-C6Me6)2Co]PF6 with nickelocene. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 798–799, April, 1999.
Keywords:triple-decker complexes  sandwich compounds  cobalt complexes  nickel complexes
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