Stereochemical features of the synthesis and the structure of fullerenes |
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Authors: | A. V. Lysenko |
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Affiliation: | (1) Department of Physics, Saratov State University, 410012 Saratov, Russia |
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Abstract: | Details of the design of decaplet fullerenes are discussed. A model of the cluster assembly of C60, C70, and C80 monomers from mono-, bi-, and trihexacyclic compounds of carbon was developed on the basis of the described structural and stereochemical concepts. The autoadhesion in the supermolecular structure, the cluster macrorecombination of the π radicals, and the contribution from spin-polymerization effects to regulation of the organic synthesis of Cn fullerenes were examined. V. N. Bakul Institute of Superhard Materials, National Academy of Sciences of Ukraine, 2 Avtozavodskaya ul., Kiev 254074, Ukraine. Translated from Teoreticheskaya i éksperimental'naya Khimiya, Vol. 35, No. 3, pp. 145–149, May–June, 1999. |
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