Thermodynamics and Thermochemistry of Organoaluminum Compounds |
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| Authors: | Baev A. K. Shishko M. A. Korneev N. N. |
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| Affiliation: | (1) Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia;(2) Nauchno-issledovatel'skii institut khimii i tekhnologii elementoorganicheskikh soedinenii, State Research Center of the Russian Federation, Moscow, Russia |
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| Abstract: | The accuracy and reliability of thermodynamic data on vaporization of trialkylaluminum, alkylaluminum hydrides, and alkylaluminum chlorides and of thermochemical data for these compounds were estimated on the basis of author's and published data. A unified system of consistent thermodynamic characteristics of the organoaluminum compounds was proposed, and the enthalpies of vaporization of a number of unstudied compounds and the dissociation energies of Al-R bonds were estimated. |
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