Kharasch reaction: Cu-catalyzed and non-Kharasch metal-free peroxidation of barbituric acids |
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| Authors: | Oleg V. Bityukov,Vera A. Vil&#x ,George K. Sazonov,Andrey S. Kirillov,Nikita V. Lukashin,Gennady I. Nikishin,Alexander O. Terent&#x ev |
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| Affiliation: | 1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation;2. D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya square, 125047 Moscow, Russian Federation |
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| Abstract: | It was discovered that the Kharasch peroxidation of barbituric acids proceeds both with a Cu-catalyst and without a metal catalyst. Despite the presence of possible thermal-initiated side oxidation pathways, α-tert-butylperoxybarbiturates were selectively prepared from substituted barbituric acids and tert-butyl hydroperoxide. |
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| Keywords: | Kharasch peroxidation Barbituric acids Corresponding author at: N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation. |
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