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Diversity of Sesquiterpenoids from Carpesium cernuum
Authors:Lei‐Lei Liu  Rui Wang  Jun‐Li Yang  Yan‐Ping Shi
Affiliation:1. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P.?R. China;2. Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P.?R. China, (phone: +86‐931‐4968208;3. fax: +86‐931‐8277088)
Abstract:Two new sesquiterpene lactones, 6β‐hydroxy‐8α‐ethoxyeremophil‐7(11)‐en‐12,8β‐olide ( 1 ) and 4β,10β‐dihydroxy‐1αH,5αH,11αH‐guaian‐12,8β‐olide ( 2 ), together with 22 known sesquiterpenoids with various structural types, were isolated from Carpesium cernuum (Compositae). Their structures and configurations were elucidated by extensive 1D‐ and 2D‐NMR spectroscopic analysis in combination with MS experiments, and comparison with literature data of related compounds.
Keywords:Lactones  Carpesium cernuum  Sesquiterpenoids
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