Conjugated oligomers with thiophene and indole moieties: Synthesis,photoluminescence and electrochromic performances |
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| Authors: | Ben Dong Baoyan Li Yi Cao Xinlei Meng Han Yan Shusheng Ge Yun Lu |
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| Institution: | Department of Polymer Science and Engineering, State Key Laboratory of Coordination Chemistry, Collaborative Innovation Center of Chemistry for Life Sciences, Key Laboratory of High Performance Polymer Materials and Technology (Nanjing University), Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, PR China |
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| Abstract: | Two series of thiophene oligomers and terthiophene oligomers consisting of both thiophene and indole moieties have been synthesized. They have same excitation-dependent photoluminescence characteristics, but different bandgaps and absorption behaviors, which relates to the number and denseness of indoles in the conjugated oligomers and the length of alkyl chains on indole moiety due to varied the π-π stacking interaction of conjugated structures in the as-prepared oligomers. A simple electrochromic device based on such a conjugated oligomer displays a novel four-color electrochromism from red to yellow, green and puce with the increased potential and possesses good environmental and redox stability. Such conjugated oligomer also exhibits high sensitivity and selectivity for Zn2+ detection. |
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| Keywords: | Conjugated oligomers Electrochromic behavior Polythiophene derivatives Chem-sensor |
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