Synthesis,crystal structure and properties of a one-dimensional polymeric copper(II) complex of tetrachlorophthalate |
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| Authors: | Yang Shi-Yao Long La-Sheng Wu Zhen-Yi Zhan Meng-Xiong Huang Rong-Bin Zheng Lan-Sun |
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| Institution: | (1) State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, 361005, People's Republic of China |
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| Abstract: | The coordination polymer Cu2L2(H2O)6 · 2(H2O)]
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(L =  -tetrachlorophthalate dianion) has been synthesized and characterized by X-ray crystallography, i.r. spectroscopy, electronic spectroscopy and cyclic voltammetry. The structure of the complex is a one-dimensional zigzag chain. The i.r. spectra reveal that the tetrachlorophthalate groups are bismonodentate ligands, and this is confirmed by the crystal structure determination. Cyclic voltammetry reveals two steps of a quasi-reversible oxidation–reduction processes for the complex. |
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