|
|||||
|
|
A Robust Metal-Organic Framework with Scalable Synthesis and Optimal Adsorption and Desorption for Energy-Efficient Ethylene Purification |
|
| Authors: | Cong Yu Zhengdong Guo Lifeng Yang Jiyu Cui Sen Chen Yawen Bo Xian Suo Qihan Gong Shang Zhang Prof Xili Cui Shengbao He Prof Huabin Xing |
| Institution: | 1. Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027 China
These authors contributed equally to this work.;2. Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027 China;3. Fundamental Science & Advanced Technology Lab, PetroChina Petrochemical Research Institute, China National Petroleum Corporation, Beijing, 102200 China;4. ZJU-Hangzhou Global Scientific and Technological Innovation Center, Hangzhou, 311215 China;5. Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027 China ZJU-Hangzhou Global Scientific and Technological Innovation Center, Hangzhou, 311215 China |
| Abstract: | Adsorptive separation is an energy-efficient alternative, but its advancement has been hindered by the challenge of industrially potential adsorbents development. Herein, a novel ultra-microporous metal-organic framework ZU-901 is designed that satisfies the basic criteria raised by ethylene/ethane (C2H4/C2H6) pressure swing adsorption (PSA). ZU-901 exhibits an “S” shaped C2H4 curve with high sorbent selection parameter (65) and could be mildly regenerated. Through green aqueous-phase synthesis, ZU-901 is easily scalable with 99 % yield, and it is stable in water, acid, basic solutions and cycling breakthrough experiments. Polymer-grade C2H4 (99.51 %) could be obtained via a simulating two-bed PSA process, and the corresponding energy consumption is only 1/10 of that of simulating cryogenic distillation. Our work has demonstrated the great potential of pore engineering in designing porous materials with desired adsorption and desorption behavior to implement an efficient PSA process. |
| Keywords: | Ethane Ethylene Gas Separation Metal-Organic Framework Pressure Swing Adsorption |