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Interfaces with Fluorinated Amphiphiles: Superstructures and Microfluidics
Authors:Florian Junge  Pin-Wei Lee  Dr Abhishek Kumar Singh  Janos Wasternack  Michał P Pachnicz  Prof Dr Rainer Haag  Christoph A Schalley
Institution:1. Institut für Chemie und Biochemie, Freie Universität Berlin, Takustrasse 3, 14195 Berlin, Germany

Contribution: ​Investigation (lead), Writing - original draft (lead);2. Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 20, 14195 Berlin, Germany;3. Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 20, 14195 Berlin, Germany

Contribution: Writing - original draft (lead);4. Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 20, 14195 Berlin, Germany

Contribution: ​Investigation (equal);5. Institut für Chemie und Biochemie, Freie Universität Berlin, Takustrasse 3, 14195 Berlin, Germany

Abstract:This Minireview discusses recent developments in research on the interfacial phenomena of fluorinated amphiphiles, with a focus on applications that exploit the unique and manifold interfacial properties associated with these amphiphiles. Most notably, fluorinated amphiphiles form stable aggregates with often distinctly different morphologies compared to their nonfluorinated counterparts. Consequently, fluorinated surfactants have found wide use in high-performance applications such as microfluidic-assisted screening. Additionally, their fluorine-specific behaviour at solid/liquid interfaces, such as the formation of superhydrophobic coatings after deposition on surfaces, will be discussed. As fluorinated surfactants and perfluorinated materials in general pose potential environmental threats, recent developments in their remediation based on their adsorption onto fluorinated surfaces will be evaluated.
Keywords:Aggregation  Amphiphiles  Fluorine  Microfluidics  Surfactants
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